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What do you think of 350z 06-07 rims being painted like this but black? matching this pattern?
I'd vote against it. The Z's rims don't cut in and make a lip like the Porsche rims do. There is somebody on here that painted thier stock rims in a paint scheme similar to what you are describing though. I recommend checking out this thread...
The Cayman S OEM wheels are made by Ronal and are modeled after the Carrera GT's wheels (as is the paint scheme). You can get the wheels painted as an (expensive) option from the dealer.
IMO, the 06-07 rims would look good if the ENTIRE rim was powdercoated gunmetal, unlike those Cayman rims. There was some one on the board that had their 06 rims powdercoated black and it looked ok...I would just powdercoat the entire rim though.